3D Study of the Morphology and Dynamics of Zeolite Nucleation

The principle aspects and constraints of the dynamics and kinetics of zeolite nucleation in hydrogel systems are analyzed on the basis of a model Na‐rich aluminosilicate system. A detailed time‐series EMT‐type zeolite crystallization study in the model hydrogel system was performed to elucidate the topological and temporal aspects of zeolite nucleation. A comprehensive set of analytical tools and methods was employed to analyze the gel evolution and complement the primary methods of transmission electron microscopy (TEM) and nuclear magnetic resonance (NMR) spectroscopy. TEM tomography reveals that the initial gel particles exhibit a core–shell structure. Zeolite nucleation is topologically limited to this shell structure and the kinetics of nucleation is controlled by the shell integrity. The induction period extends to the moment when the shell is consumed and the bulk solution can react with the core of the gel particles. These new findings, in particular the importance of the gel particle shell in zeolite nucleation, can be used to control the growth process and properties of zeolites formed in hydrogels.     

DABCO-based ionic liquids:Green and efficient catalysts with a dual catalytic role for aza-Michael addition

Four recoverable and reusable ionic liquids based on 1,4-diazobicyclo[2.2.2]octane(DABCO) have been synthesized to catalyze the aza-Michael addition of secondary amines to a,b-unsaturated compounds.Among the catalysts tested,[DABCO-PDO][OAc] was found to be most suitable for the reaction of a wide range of cyclic substrates without any solvent at room temperature,and afford the products in good to excellent yields within an appropriate amount of time.The proposed mechanism for the dual activation of the catalyst was supported by experimental results as well as the DFT calculation.In addition,the ionic liquids used can be regenerated and recycled several times without any loss of activity.     

Redox‐Neutral α‐Allylation of Amines by Combining Palladium Catalysis and Visible‐Light Photoredox Catalysis

An unprecedented α‐allylation of amines was achieved by combining palladium catalysis and visible‐light photoredox catalysis. In this dual catalysis process, the catalytic generation of allyl radical from the corresponding π‐allylpalladium intermediate was achieved without additional metal reducing reagents (redox‐neutral). Various allylation products of amines were obtained in high yields through radical cross‐coupling under mild reaction conditions. Moreover, the transformation was applied to the formal synthesis of 8‐oxoprotoberberine derivatives which show potential anticancer properties.     

Solvability of 2n-order m-point boundary value problem at resonance

The existence of solutions for the 2n-order m-point boundary value problem at resonance is obtained by using the coincidence degree theory of Mawhin.We give an example to demonstrate our result.The interest is that the nonlinear term may be noncontinuous.     

DYNAMIC SIMULATION ANALYSIS OF CAPTURE AND BUFFER SYSTEM BASED ON CLAW-TYPE DOCKING MECHANISM

现有在轨服务的对接机构由于其尺寸大、结构复杂、对接目标单一等局限性因素,无法很好地为后续我国探月工程任务提供有力支撑,且受限于运载能力,对接机构的轻量化也是必不可少的一项环节.为研究可服务于未来月球空间站以及载人登月等高轨道任务的对接机构,设计了一种新型抱爪式对接机构,其采用异体同构周边式构型,可以实现主/被动飞行器之间的互换.利用 V 型槽与爪钩等结构部件实现飞行器对接过程中的捕获以 及能量消耗功能,从而实现两飞行器之间的稳固联接.该对接机构具备尺寸小、重量轻、结构简单、功能易实现等优势. 对其捕获缓冲系统进行了动力学分析,计算了缓冲元器件的参数对其捕获性能的影响,在 ADAMS 完成了数字虚拟样机的建立,结合实际两种典型的对接初始条件工况进行了仿真研究.研究结果表明,两种工况下的对接过程能量消耗满足设计要求,能够以较小的 V 型槽的碰撞力完成捕获,结果证明了捕获缓冲系统的可行性以及该构型对接机构具备较好实现任务的能力.     

不确定非线性结构动力响应的区间分析方法

研究多自由度非线性不确定参数系统的动力响应问题. 以区间数学为基础，将不确定 性参数用区间进行定量化，借助一阶Taylor级数，给出了近似估计非线性振动系统动力响 应范围的区间分析方法. 从数学证明和数值算例两方面，将其与概率摄动有限元法进行了比 较，结果显示区间分析方法对不确定参数先验信息具有要求较少、精度较高的优点.     

The impact of high order refraction on optical microbubble sizing in multiphase flows

High order refractions have been found to have a great impact on optical particle sizing using phase-Doppler anemometry (PDA) especially when the relative refractive index of the media is less than one. The high order refractions cannot be neglected because of the differences in spatial frequencies and motion directions of each order. A model of phase-size correlation is proposed that considers these high order refractions. By using the conversion factors of the high order refractions, the particle diameter can be determined. The capability of the newly developed method was evaluated by using generalized Lorenz Mie theory (GLMT), which was validated by experiments. The results of the simulation and experiments are compared with those based on the conventional method. An optimization method for accurately sizing air bubbles in water has been suggested.     

一阶非线性项、四阶色散项的Boussinesq类方程

推导了由一阶色散项Ｏ（β２）表示的Ｂｏｕｓｉｎｅｓｑ类方程，方程中保留了一阶非线性项Ｏ（α）及四阶色散项Ｏ（β８），其中α＝Ａ／ｈ０，β＝ｈ０／Ｌ，Ａ为特征波高，Ｌ为特征波长，ｈ０为特征水深从理论上证明了Ｂｏｕｓｉｎｅｓｑ改善型方程对色散性精度的提高，阐明了此类方程对色散项所保留的精度为Ｏ（β８），而并非是此类方程推导之初的假设为Ｏ（β２）这一点，将改变人们传统的认识